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- W1989448894 abstract "Abstract A new M-MOF-74 material, with M being cadmium, is described. The so-called Cd-MOF-74 material was prepared under solvothermal conditions using cadmium acetate as metal source. It was characterized by a variety of physico-chemical techniques including PXRD, TGA, N 2 adsorption–desorption isotherms, SEM, IR and multinuclear solid-state NMR. Although the quality and/or the size of the afforded crystals did not allow us solving the structure by single-crystal X-ray diffraction, the information given by different characterization techniques is enough to confirm that the sample is indeed a Cd-based MOF-74-like material. Fingerprint-based PXRD and FTIR techniques showed a good matching between the Cd-MOF-74 and the well-known Zn-MOF-74 samples. Likewise, TGA and N 2 adsorption–desorption at 196 °C gave expected values of Cd/linker ratio and textural properties, respectively. SEM certified the homogeneity of crystals and the absence of impurities. Among the divalent metal ions capable to produce MOF-74 materials, Cd 2+ presents some singularities: (i) it is the first metal of the second transition metal row able to led to a M-MOF-74 material; (ii) due to reasonably good magnetic properties of the diamagnetic non-quadrupolar 113 Cd and 111 Cd nuclei, metal-adsorbate interactions can be studied from a metal point of view by means of NMR techniques." @default.
- W1989448894 created "2016-06-24" @default.
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- W1989448894 date "2014-05-01" @default.
- W1989448894 modified "2023-09-29" @default.
- W1989448894 title "Synthesis and characterization of a new Cd-based metal-organic framework isostructural with MOF-74/CPO-27 materials" @default.
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- W1989448894 doi "https://doi.org/10.1016/j.micromeso.2014.02.021" @default.
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