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- W1989472259 abstract "Abstract Linear, soluble copolymers of vinyl isocyanate with styrene and methyl methacrylate were obtained when the comonomer:vinyl isocyanate ratio in the copolymer was greater than 9:1. When the comonomer to isocyanate ratio was less than 2:1, the copolymers were insoluble. Infrared evidence indicated that spontaneous cross-linking through the isocyanate function occurred by a mechanism similar to the known reaction by which isocyanates undergo dimerization and trimerization. The soluble copolymers retained the reactive isocyanate moeity as was shown by their reactivity with n-butylamine and ethanol to produce, respectively, the corresponding polyurea and polycarbamate, and with ethylenediamine and water to produce cross-linked polymers. The intrinsic viscosity [η] for the 9:1 methyl methacrylate: vinyl isocyanate copolymer was 0.22 dl/g while that for the corresponding ethyl carbamate was 0.24 dl/g." @default.
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- W1989472259 date "1971-10-01" @default.
- W1989472259 modified "2023-10-06" @default.
- W1989472259 title "Some Reactions of Vinyl Isocyanate and Its Copolymers∗" @default.
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- W1989472259 doi "https://doi.org/10.1080/00222337108061090" @default.
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