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- W1989511405 abstract "Carbonylbis(η-cyclopentadienyl)hydridoniobium (I) Cp2NbH(CO) reacts with MeO2CCCCO2Me at −80°C to give predominantly the (Z)-alkenyl complex Cp2Nb(CO)[η1-(Z)-C(CO2Me)CH(CO2R)] (II), together with the E isomer (III) in a 31 ratio. Slow isomerization at ambient temperature produces a 15 equilibrium mixture. The structure of II was determined by X-ray diffraction methods. Activated terminal acetylenes HCCR undergo α-insertion to yield the alkenyl complexes Cp2Nb(CO)[η1-(CRCH2)] (IV, R = CO2, Me; V, R = C(O)Me)." @default.
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- W1989511405 date "1988-06-01" @default.
- W1989511405 modified "2023-10-18" @default.
- W1989511405 title "Insertion reactions of carbonylbis(η-cyclopentaidenyl)-hydridoniobium with activated acetylenes" @default.
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- W1989511405 doi "https://doi.org/10.1016/0022-328x(88)80273-0" @default.
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