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- W1989533714 abstract "The EPR g factors of Cr 3+ in NaCrS 2 and NaCrSe 2 crystals are calculated from the high-order perturbation formulas based on the one-spin-orbit (SO)-coupling-parameter (i. e., the SO-couplingparameter of the central 3d n ion) as well as the two-SO-coupling-parameter (i. e., the SO-couplingparameter of the 3d n ion and that of ligands) models for 3d n ions in cubic octahedral sites. The calculated results (in particular for NaCrSe 2 ) based on the two-SO-coupling-parameter model are closer to the observed values than those based on the one-SO-coupling-parameter model, suggesting that for calculations of the g factor of 3d n ions in covalent crystals the two-SO-coupling-parameter model is preferable to the one-SO-coupling-parameter model. The reasonableness of the calculated results from the two-SO-coupling-parameter model is discussed." @default.
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- W1989533714 date "2005-05-01" @default.
- W1989533714 modified "2023-09-25" @default.
- W1989533714 title "Investigations Of The Epr G Factors Of Nacrs2 And Nacrse2" @default.
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- W1989533714 doi "https://doi.org/10.1515/zna-2005-0508" @default.
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