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- W1989595823 abstract "High-precision measured values of g∥ for Gd3+ dilutely substituted in single crystals of 13 lanthanide ethyl sulfate nonahydrates at room temperature (297.3 K) are presented. It is shown that, within the experimental uncertainties, the present observations are entirely accounted for in terms of a model invoking purely magnetic dipolar interactions between the Gd3+ guests and the host structures. On this model, the shift of g∥ depends upon the identity of the lanthanide host, the sample shape, the temperature, and the Gd3+ composition. Moreover, values of the shifts of g∥ at 77.2 K predicted by this model are in agreement, within the experimental uncertainties, with the 77.2 K data of Gerkin and Thorsell [J. Chem. Phys. 57, 2665 (1972)]. Consistent with this model, values of g∥ for spherical samples of 2.0×10−3 mole fraction Gd3+ in 14 of the lanthanide ethyl sulfate nonahydrates at 297.3 K and at 77.2 K are presented." @default.
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- W1989595823 date "1978-01-15" @default.
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- W1989595823 title "EPR spectroscopic determination and interpretation of <i>g</i>∥ of Gd3+ in single crystals of the lanthanide ethyl sulfate nonahydrates" @default.
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- W1989595823 doi "https://doi.org/10.1063/1.435759" @default.
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