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- W1989624225 abstract "FVP of the title alcohol ( 9 ) at 0.65 mbar in argon atmosphere at 350 °C in the presence of seven different acidic zeolites afforded 7H-benzo[ c ]fluorene ( 13 ) and 6,11b-dihydro-7H-ben-zo [ c ]fluorene ( 12 ) as main reaction products. The suggested carbocationic reaction mechanism is supported by: 1. (a) the occurrence of two isomeric dibenzo(C 9 H 10 )hydrocarbons, namely 1,1a,6,10b-tetrahydro-1,6-methanodibenzo[ a , e ]cyclopropa[ c ]cycloheptene ( 6 ) and 9,10-dihydro-9,10-propenoanthracene ( 5 ), in the pyrolyses of 9 and 2. (b) by the results of FVP of authentic samples of 6 (conducting mainly to hydrocarbons 12 and 13 ), respectively 5 (affording to greatest extent the minor products observed in pyrolyses of 9 )." @default.
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- W1989624225 date "1997-07-01" @default.
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- W1989624225 title "Flash vacuum pyrolysis (FVP) on zeolites: Pyrolysis of 5-β (hydroxyethyl)-5H-dibenzo[a,d]cycloheptene" @default.
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- W1989624225 doi "https://doi.org/10.1016/s0165-2370(97)00037-5" @default.
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