Matches in SemOpenAlex for { <https://semopenalex.org/work/W1989681242> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W1989681242 endingPage "12935" @default.
- W1989681242 startingPage "12934" @default.
- W1989681242 abstract "Treatment of [σ:η5-(C9H6)C2B9H10]Zr(NMe2)(DME) with 2 equiv of guanidines iPrNHC(NR2)NiPr (R = Me, Et) in refluxing toluene gave unprecedented complexes [η1:σ:η5-{2-[CNiPr(NHiPr)]C9H5}C2B9H10]Zr[η2-(iPrN)2C(NR2)] (R = Me, Et). This communication describes the mechanism by which they are formed. Experimental results show that guanidinates are not inert ligands in the present cases that can undergo C−N bond cleavage to generate amido and carbodiimide that subsequently insert into the Zr−C bond to form the final product via 1,5-sigmatropic shift." @default.
- W1989681242 created "2016-06-24" @default.
- W1989681242 creator A5006980400 @default.
- W1989681242 creator A5022280289 @default.
- W1989681242 creator A5078892060 @default.
- W1989681242 date "2007-10-01" @default.
- W1989681242 modified "2023-10-01" @default.
- W1989681242 title "Reaction of [σ:η<sup>5</sup>-(C<sub>9</sub>H<sub>6</sub>)C<sub>2</sub>B<sub>9</sub>H<sub>10</sub>]Zr(NMe<sub>2</sub>)(DME) with Guanidines: Metallacarborane-Mediated C−N Bond Cleavage and 1,5-Sigmatropic Rearrangement" @default.
- W1989681242 cites W1975650978 @default.
- W1989681242 cites W40791781 @default.
- W1989681242 doi "https://doi.org/10.1021/ja0754498" @default.
- W1989681242 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17918846" @default.
- W1989681242 hasPublicationYear "2007" @default.
- W1989681242 type Work @default.
- W1989681242 sameAs 1989681242 @default.
- W1989681242 citedByCount "46" @default.
- W1989681242 countsByYear W19896812422012 @default.
- W1989681242 countsByYear W19896812422013 @default.
- W1989681242 countsByYear W19896812422014 @default.
- W1989681242 countsByYear W19896812422015 @default.
- W1989681242 countsByYear W19896812422016 @default.
- W1989681242 countsByYear W19896812422017 @default.
- W1989681242 countsByYear W19896812422019 @default.
- W1989681242 countsByYear W19896812422020 @default.
- W1989681242 countsByYear W19896812422021 @default.
- W1989681242 countsByYear W19896812422022 @default.
- W1989681242 crossrefType "journal-article" @default.
- W1989681242 hasAuthorship W1989681242A5006980400 @default.
- W1989681242 hasAuthorship W1989681242A5022280289 @default.
- W1989681242 hasAuthorship W1989681242A5078892060 @default.
- W1989681242 hasConcept C127413603 @default.
- W1989681242 hasConcept C154256306 @default.
- W1989681242 hasConcept C155647269 @default.
- W1989681242 hasConcept C161790260 @default.
- W1989681242 hasConcept C175156509 @default.
- W1989681242 hasConcept C178790620 @default.
- W1989681242 hasConcept C185592680 @default.
- W1989681242 hasConcept C187320778 @default.
- W1989681242 hasConcept C196099240 @default.
- W1989681242 hasConcept C2775997276 @default.
- W1989681242 hasConcept C2778142098 @default.
- W1989681242 hasConcept C3044715 @default.
- W1989681242 hasConcept C43369102 @default.
- W1989681242 hasConcept C68381374 @default.
- W1989681242 hasConcept C71240020 @default.
- W1989681242 hasConceptScore W1989681242C127413603 @default.
- W1989681242 hasConceptScore W1989681242C154256306 @default.
- W1989681242 hasConceptScore W1989681242C155647269 @default.
- W1989681242 hasConceptScore W1989681242C161790260 @default.
- W1989681242 hasConceptScore W1989681242C175156509 @default.
- W1989681242 hasConceptScore W1989681242C178790620 @default.
- W1989681242 hasConceptScore W1989681242C185592680 @default.
- W1989681242 hasConceptScore W1989681242C187320778 @default.
- W1989681242 hasConceptScore W1989681242C196099240 @default.
- W1989681242 hasConceptScore W1989681242C2775997276 @default.
- W1989681242 hasConceptScore W1989681242C2778142098 @default.
- W1989681242 hasConceptScore W1989681242C3044715 @default.
- W1989681242 hasConceptScore W1989681242C43369102 @default.
- W1989681242 hasConceptScore W1989681242C68381374 @default.
- W1989681242 hasConceptScore W1989681242C71240020 @default.
- W1989681242 hasIssue "43" @default.
- W1989681242 hasLocation W19896812421 @default.
- W1989681242 hasLocation W19896812422 @default.
- W1989681242 hasOpenAccess W1989681242 @default.
- W1989681242 hasPrimaryLocation W19896812421 @default.
- W1989681242 hasRelatedWork W1978306567 @default.
- W1989681242 hasRelatedWork W1989681242 @default.
- W1989681242 hasRelatedWork W2053120620 @default.
- W1989681242 hasRelatedWork W2053825085 @default.
- W1989681242 hasRelatedWork W2071510621 @default.
- W1989681242 hasRelatedWork W2139783973 @default.
- W1989681242 hasRelatedWork W2522289457 @default.
- W1989681242 hasRelatedWork W2775395077 @default.
- W1989681242 hasRelatedWork W2950868961 @default.
- W1989681242 hasRelatedWork W4289203488 @default.
- W1989681242 hasVolume "129" @default.
- W1989681242 isParatext "false" @default.
- W1989681242 isRetracted "false" @default.
- W1989681242 magId "1989681242" @default.
- W1989681242 workType "article" @default.