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• W1989682801 endingPage "6691" @default.
• W1989682801 startingPage "6691" @default.
• W1989682801 abstract "A highly efficient enantioselective aryl addition to aldehydes using boroxins as aryl source and conformationally restricted perhydro-1,3-benzoxazines as ligands is reported. Both enantiomeric forms of chiral arylphenylmethanols and 1,1'-disubstituted diarylmethanols are afforded with excellent yields and enantioselectivities using the same ligand by means of an appropriate combination of boroxin and aromatic aldehyde. The enantiocontrol is not significantly influenced by electronic effects or steric hindrance, even with substituted boroxins. Very homogeneous ee's are reached when substituted arylboroxins are employed, without the use of any class of additive or pre-treatment." @default.
• W1989682801 created "2016-06-24" @default.
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• W1989682801 creator A5019257540 @default.
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• W1989682801 date "2011-01-01" @default.
• W1989682801 modified "2023-09-29" @default.
• W1989682801 title "Asymmetric additive-free aryl addition to aldehydes using perhydrobenzoxazines as ligands and boroxins as aryl source" @default.
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• W1989682801 doi "https://doi.org/10.1039/c1ob05717k" @default.
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