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- W1989707777 abstract "Abstract 1,2,4,6-Tetra-O-acetyl-3-O-benzyl-α- D -mannopyranose (7) was obtained in good yield from 3,4,6-tri-O-benzyl-1,2-O-(1-methoxyethylidene)-β- D -mannopyranose (1) by acetolysis. Hydrogenolysis of 7 afforded 1,2,4,6-tetra-O-acetyl-α- D -mannopyranose which is a versatile intermediate for the preparation of other 3-O-substituted D -mannoses, such as 3-O-methyl- D -mannose and 3-O-α- D -mannopyranosyl- D -mannose. 3,4-Di-O-methyl- D -mannose was readily prepared from 1,2,6-tri-O-acetyl-3,4-di-O-benzyl-α- D -mannopyranose, which was also obtained from 1 by controlled acetolysis." @default.
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- W1989707777 date "1977-12-01" @default.
- W1989707777 modified "2023-09-27" @default.
- W1989707777 title "Synthesis of 3-O Substituted D-Mannoses" @default.
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- W1989707777 doi "https://doi.org/10.1016/s0008-6215(00)83173-0" @default.
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