Matches in SemOpenAlex for { <https://semopenalex.org/work/W1989715423> ?p ?o ?g. }
- W1989715423 endingPage "5175" @default.
- W1989715423 startingPage "5167" @default.
- W1989715423 abstract "The reaction of carbon dioxide with the stannane nBu2Sn(OiPr)2 and distannoxane [nBu2(iPrO)Sn]2O leads to the selective insertion into one Sn-OiPr bond generating the corresponding nBu2Sn(OiPr)(OCO2(i)Pr) and nBu2(iPrO)SnOSn(OCO2(i)Pr)nBu2 species. Both compounds are characterised by multinuclear NMR, FT-IR and single-crystal X-ray crystallography. In the solid state, they adopt a dimeric arrangement with bridging isopropoxy and terminal isopropylcarbonato ligands. The X-ray crystal structure of the dinuclear stannane shows that the Sn2O2 ring and the two Sn-OCO2C fragments are nearby coplanar. The same holds for the ladder-type tetranuclear distannoxane. The dimeric structures are also evidenced by solution NMR in non-coordinating solvents. Interestingly, the assignment of the exo and endo tin resonances of the dimeric distannoxane is unambiguous using a labeled 13CO2 experiment. The stability of the dimeric association has been probed in the stannane series on the basis of DFT calculations." @default.
- W1989715423 created "2016-06-24" @default.
- W1989715423 creator A5028535289 @default.
- W1989715423 creator A5033266058 @default.
- W1989715423 creator A5044435991 @default.
- W1989715423 creator A5056366336 @default.
- W1989715423 date "2006-01-01" @default.
- W1989715423 modified "2023-10-16" @default.
- W1989715423 title "Insertion reaction of carbon dioxide into Sn–OR bond. Synthesis, structure and DFT calculations of di- and tetranuclear isopropylcarbonato tin(<scp>iv</scp>) complexes" @default.
- W1989715423 cites W152678465 @default.
- W1989715423 cites W1966066407 @default.
- W1989715423 cites W1973639779 @default.
- W1989715423 cites W1989322126 @default.
- W1989715423 cites W1999961126 @default.
- W1989715423 cites W2001523784 @default.
- W1989715423 cites W2002782178 @default.
- W1989715423 cites W2005809456 @default.
- W1989715423 cites W2010951869 @default.
- W1989715423 cites W2012346846 @default.
- W1989715423 cites W2015957453 @default.
- W1989715423 cites W2016553808 @default.
- W1989715423 cites W2017063849 @default.
- W1989715423 cites W2018754399 @default.
- W1989715423 cites W2022765376 @default.
- W1989715423 cites W2028818325 @default.
- W1989715423 cites W2029259808 @default.
- W1989715423 cites W2029667236 @default.
- W1989715423 cites W2030841140 @default.
- W1989715423 cites W2036608037 @default.
- W1989715423 cites W2039358208 @default.
- W1989715423 cites W2040663511 @default.
- W1989715423 cites W2045251523 @default.
- W1989715423 cites W2047986698 @default.
- W1989715423 cites W2054583981 @default.
- W1989715423 cites W2059532603 @default.
- W1989715423 cites W2076533752 @default.
- W1989715423 cites W2077871424 @default.
- W1989715423 cites W2079450709 @default.
- W1989715423 cites W2085959629 @default.
- W1989715423 cites W2090062745 @default.
- W1989715423 cites W2091680897 @default.
- W1989715423 cites W2094387829 @default.
- W1989715423 cites W2098038251 @default.
- W1989715423 cites W2103857876 @default.
- W1989715423 cites W2132815010 @default.
- W1989715423 cites W2150345533 @default.
- W1989715423 cites W2150535145 @default.
- W1989715423 cites W2161652710 @default.
- W1989715423 cites W2318125934 @default.
- W1989715423 cites W2327567397 @default.
- W1989715423 cites W2333296134 @default.
- W1989715423 cites W2493062013 @default.
- W1989715423 cites W3136188539 @default.
- W1989715423 doi "https://doi.org/10.1039/b610812a" @default.
- W1989715423 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17077890" @default.
- W1989715423 hasPublicationYear "2006" @default.
- W1989715423 type Work @default.
- W1989715423 sameAs 1989715423 @default.
- W1989715423 citedByCount "50" @default.
- W1989715423 countsByYear W19897154232012 @default.
- W1989715423 countsByYear W19897154232013 @default.
- W1989715423 countsByYear W19897154232014 @default.
- W1989715423 countsByYear W19897154232015 @default.
- W1989715423 countsByYear W19897154232016 @default.
- W1989715423 countsByYear W19897154232017 @default.
- W1989715423 countsByYear W19897154232018 @default.
- W1989715423 countsByYear W19897154232019 @default.
- W1989715423 countsByYear W19897154232020 @default.
- W1989715423 countsByYear W19897154232021 @default.
- W1989715423 crossrefType "journal-article" @default.
- W1989715423 hasAuthorship W1989715423A5028535289 @default.
- W1989715423 hasAuthorship W1989715423A5033266058 @default.
- W1989715423 hasAuthorship W1989715423A5044435991 @default.
- W1989715423 hasAuthorship W1989715423A5056366336 @default.
- W1989715423 hasConcept C115624301 @default.
- W1989715423 hasConcept C178790620 @default.
- W1989715423 hasConcept C185592680 @default.
- W1989715423 hasConcept C2777897746 @default.
- W1989715423 hasConcept C2780378348 @default.
- W1989715423 hasConcept C525849907 @default.
- W1989715423 hasConcept C71240020 @default.
- W1989715423 hasConcept C8010536 @default.
- W1989715423 hasConceptScore W1989715423C115624301 @default.
- W1989715423 hasConceptScore W1989715423C178790620 @default.
- W1989715423 hasConceptScore W1989715423C185592680 @default.
- W1989715423 hasConceptScore W1989715423C2777897746 @default.
- W1989715423 hasConceptScore W1989715423C2780378348 @default.
- W1989715423 hasConceptScore W1989715423C525849907 @default.
- W1989715423 hasConceptScore W1989715423C71240020 @default.
- W1989715423 hasConceptScore W1989715423C8010536 @default.
- W1989715423 hasIssue "43" @default.
- W1989715423 hasLocation W19897154231 @default.
- W1989715423 hasLocation W19897154232 @default.
- W1989715423 hasLocation W19897154233 @default.
- W1989715423 hasLocation W19897154234 @default.
- W1989715423 hasOpenAccess W1989715423 @default.
- W1989715423 hasPrimaryLocation W19897154231 @default.
- W1989715423 hasRelatedWork W1972899349 @default.