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• W1989722941 endingPage "1411" @default.
• W1989722941 startingPage "1402" @default.
• W1989722941 abstract "The synthesis, X-ray structure and properties of a pentanuclear cobalt(III) coordination cluster [{L(O2CCH3)Co2O(OCH3)2}2Co](ClO4)3 (1) (L− = 2,6-bis((3-aminopropylimino)methyl)-4-methylphenolate) are described. The dinucleating L− is coordinated with two cobalt(III) centers to form the {L(O2CCH3)Co2O(OCH3)2} unit, where each metal center is in a distorted octahedral N2O4 environment. The oxo and the methoxo ligands of these two dinuclear units assemble a distorted octahedral O6 coordination sphere around the central cobalt(III). Elemental analysis and spectroscopic (IR, NMR, UV–vis, and HRMS) features are consistent with the pentanuclear structure of the complex. The diamagnetic complex is a 1 : 3 electrolyte in solution. It is redox-active and displays a metal-centered reduction at E1/2 = −0.04 V (vs. Ag/AgCl)." @default.
• W1989722941 created "2016-06-24" @default.
• W1989722941 creator A5009539141 @default.
• W1989722941 creator A5037920440 @default.
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• W1989722941 date "2015-03-12" @default.
• W1989722941 modified "2023-09-27" @default.
• W1989722941 title "Synthesis, structure, and properties of a pentanuclear cobalt(III) coordination cluster" @default.
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• W1989722941 doi "https://doi.org/10.1080/00958972.2015.1018195" @default.
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