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- W1989733077 abstract "This contribution describes a number of linear enthalpy/entropy compensations found with various ion-pair reversed-phase high-performance liquid-solid chromatographic (RP-HPLSC) arrangements. Similar plots for these systems and for those described by non-ion-pair arrangements can be described, and analysis of these compensations in functional group terms indicates that differences in compensation plots are probably due to differences in phase ratios. Time and hydrophobic normalisation, and other extrathermodynamic approaches have been employed to study the effect of organic modifier on phase selectivity in ion-pair systems. The observation of a concomitant behavioural effect by temperature and eluent composition on retention of solutes in such systems has been analysed according to previously described models and it is demonstrated that for ion-pair RP-HPLC there exists a structurally dependent non-compensated residue for the enthalpy of retention. It is suggested that these residues are responsible for observed perturbations in a general enthalpy/entropy compensation relationship for RP-HPLSC." @default.
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- W1989733077 date "1981-11-01" @default.
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- W1989733077 title "Structural effects in enthalpy/entropy compensated and non-compensated behaviour in ion-pair reversed-phase high-performance liquid-solid chromatography" @default.
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- W1989733077 doi "https://doi.org/10.1016/s0021-9673(00)82069-5" @default.
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