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- W1989735814 abstract "In solution, the digermene Ar2GeGeAr2 (Ar = 2-tBu-4,5,6-Me3C6H) partly dissociates into two molecules of the germylene Ar2Ge:. The reaction of this digermene with some 1,3-diynes (RC⋮C−)2 leads to the formation of the acetylene-linked bis(germaethenes) Ar2GeC(R)C⋮C(R)CGeAr2 (R = n-C4H9 (6a), C6H5 (6b)). The conjugation between the two GeC units is reflected by the positions of the UV/vis absorptions at longest wavelengths of 518 (6a) and 595 (6b) nm. An X-ray structure analysis of 6a reveals a nearly linear C4 skeleton and short GeC bond lengths of 1.819(2) Å." @default.
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- W1989735814 date "2000-06-22" @default.
- W1989735814 modified "2023-10-18" @default.
- W1989735814 title "Acetylene-Linked Bis(germaethenes): The First Molecules with Conjugated Germanium−Carbon Double Bonds<sup>1</sup>" @default.
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- W1989735814 doi "https://doi.org/10.1021/om000284w" @default.
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