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- W1989763790 abstract "The mechanism of free radical grafting of styrene–acrylonitrile with polybutadiene was studied. By assuming a copolymerization mechanism an equation that related the amount of homopolymer formed and its molecular weight to a reactivity ratio and the charged ratio of monomer to polydiene was derived. Polymerizations that contained a variety of ratios of monomer to polybutadiene, two different catalysts, and variable amounts of a mercaptan modifier were studied. The weight fraction of homopolymer and its molecular weight were determined by high-speed GPC. The results were analyzed by the new equation and all showed a constant value of the reactivity ratio, which strongly suggests that the mechanism of the grafting reaction is copolymerization. Evidence that suggests that none of the grafting is a result of a hydrogen abstraction mechanism is also presented." @default.
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- W1989763790 date "1981-04-01" @default.
- W1989763790 modified "2023-10-17" @default.
- W1989763790 title "Kinetics and mechanism of the polymerization of styrene–acrylonitrile in the presence of polybutadiene" @default.
- W1989763790 doi "https://doi.org/10.1002/pol.1981.170190412" @default.
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