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- W1989845792 abstract "The reflection coefficient of HCl of a cation exchange membrane separating two homogeneous aqueous solutions containing HCl and NaCl [c' (HCl) = 5 × 10−3c+, c” (HCl) = 2 × 10−2c+; c' (NaCl) = c” (NaCl) = c (NaCl): 0≤c (NaCl)≤0.5c+; c+ = 1 mol dm−3] exhibits a characteristic dependence on the concentration of NaCl. In the absence of NaCl the reflection coefficient σ(HCl) has a value close to 1. With increasing values of the concentration of NaCl the value of the reflection coefficient σ(HCl) increases and reaches a maximum value of about σ(HCl) ≈︁ 2.5 at [c (NaCl)/〈c (HCl)〉] ≈︁ 5.0. Above this value the reflection coefficient σ(HCl) decreases reaching values of σ(HCl) ≈︁ 1 at values of [c (NaCl)/〈c (HCl)〉] ≈︁ 45. This concentration dependence of σ(HCl) is in qualitative agreement with recent theoretical predictions and independent calculations based on the model of the membrane with narrow pores." @default.
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- W1989845792 date "1993-05-01" @default.
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- W1989845792 title "Osmotic Properties of a Cation Exchange Membrane: Reflection Coefficients of a Solute Larger than 1 in a System with Aqueous Mixed Electrolyte Solutions" @default.
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- W1989845792 doi "https://doi.org/10.1002/bbpc.19930970506" @default.
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