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- W1989895134 abstract "In this study the synthesis of novel chiral calix[4]azacrown derivatives has been reported. The enantioselectivity of chiral receptors was investigated by using UV–vis spectroscopy. All the chiral calix[4]arene derivatives exhibited certain chiral recognition toward the enantiomers of phenylalanine (Phe-OMe·HCl) and alanine methyl ester hydrochlorides (Ala-OMe·HCl). As a chiral receptor, the furfuryl-armed calix[4]azacrown ether 7 has the best enantiomeric discriminating ability for α-amino acid ester hydrochlorides (up to KL/KD=2.08, ΔΔG0=−1.82 kJ mol−1) in CHCl3. The enantiomeric recognition abilities for guests are also discussed from a thermodynamic point of view." @default.
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- W1989895134 date "2009-04-01" @default.
- W1989895134 modified "2023-10-14" @default.
- W1989895134 title "Chiral calix[4]azacrowns for enantiomeric recognition of amino acid derivatives" @default.
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- W1989895134 doi "https://doi.org/10.1016/j.tet.2009.01.087" @default.
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