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• W1989986506 abstract "Monte Carlo simulations have been performed for the linear tangent hard sphere model. The models considered in this work consisted of m=3, 4, 5, 6, and 7 monomer units. For the models m=3 and m=4 we find an isotropic fluid and an ordered solid. For the m=5 model we find the sequence of phases isotropic–nematic–smectic A on compression, and the sequence solid–smectic A–isotropic on expansion. We suggest that the nematic phase for this model is meta stable. For the model m=6 we observe the phase sequence isotropic–nematic–smectic A on compression, and the sequence ordered solid–smectic A–nematic–isotropic on expansion. We observe a similar sequence on expansion of the m=7 model. The results for the m=7 model are in good agreement with those of Williamson and Jackson [J. Chem. Phys. 108, 10294 (1998)]. It was suggested by Flory [Proc. R. Soc. London, Ser. A 234, 73 (1956)] that liquid crystal phases could exist for length to breadth ratios ⩾5.437, i.e., m⩾6. In this work we place the lower bound at m⩾5." @default.
• W1989986506 created "2016-06-24" @default.
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• W1989986506 date "2001-09-01" @default.
• W1989986506 modified "2023-10-12" @default.
• W1989986506 title "Liquid crystal phase formation for the linear tangent hard sphere model from Monte Carlo simulations" @default.
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• W1989986506 doi "https://doi.org/10.1063/1.1389095" @default.
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