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• W1990002918 abstract "The Electron Paramagnetic Resonance (EPR) of Mn4+ in the rhombohedral low- temperature phase of BaTiO3 has been observed at 19.3 and 13.0 GHz. The spectra have axial symmetry along 〈111〉 directions. Intensity measurements prove that the Mn4+ EPR reflects {111} domain orientation. The spin-Hamiltonian constants are g‖=1.9968(19), g‖=2.0015(5), A‖=67.48(5)×10−4cm−1, A‖=73.04(15)×10−4cm−1, and D=0.65(1)cm−1 at 4.2 K. The very large D value is more than 20 times that found for the isoelectronic Cr3+. The latter ion remains centered in its surrounding octahedral oxygen cage, whereas the Mn4+ is off-center with similar coordinates as Ti4+. This result is deduced from a superposition-model analysis." @default.
• W1990002918 created "2016-06-24" @default.
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• W1990002918 date "1987-01-01" @default.
• W1990002918 modified "2023-10-14" @default.
• W1990002918 title "Electron paramagnetic resonance of Mn4+ in BaTiO3" @default.
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• W1990002918 doi "https://doi.org/10.1016/0038-1098(87)90007-x" @default.
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