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- W1990012766 endingPage "5001" @default.
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- W1990012766 abstract "A series of five ortho-lithiated imines (Li-Ln; n = 1–5) was synthesized via the reaction of an aryl or alkyl acetophenone imine with n-butyllithium. The ortho-lithiated imines were subsequently reacted with Ti(NR)Cl2py3 (R = C(CH3)3, 2,6-Me2C6H3, 2,6-Et2C6H3, or 2,6-iPr2C6H3), yielding complexes of the form (Ln)2Ti(NR). Several of the resulting complexes [(L1)2Ti(NC(CH3)3), 1a; (L3)2Ti(N-2,6-Me2C6H3), 3b; and (L5)2Ti(NC(CH3)3), 5a] were structurally characterized using small molecule X-ray diffraction. The C2 symmetric complexes produced in these reactions displayed a distorted square pyramidal geometry. In each complex the titanium center was located above the square plane of the two coordinated bidentate ligands and the chelating C∼N ligands were folded away from the metal center. When a less sterically demanding alkylimine was used (L4), the resulting complex was isolated as an equilibrium mixture of cis and trans isomers of the empirical formula (L4)2Ti(NC(CH3)3)py (cis/trans4a)." @default.
- W1990012766 created "2016-06-24" @default.
- W1990012766 creator A5040109708 @default.
- W1990012766 creator A5050927981 @default.
- W1990012766 creator A5071067237 @default.
- W1990012766 creator A5079343062 @default.
- W1990012766 date "2009-01-01" @default.
- W1990012766 modified "2023-10-18" @default.
- W1990012766 title "Titanium imido complexes utilizing orthometallated derivatized acetophenone and piperonal imine ligands: synthesis, isolation, and characterization" @default.
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- W1990012766 doi "https://doi.org/10.1039/b906461c" @default.
- W1990012766 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19662292" @default.
- W1990012766 hasPublicationYear "2009" @default.
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