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- W1990023478 abstract "Melamine (M) forms hydrogen bonded adducts with the N-heterocycles tris(2-pyridyl)-triazine (TPTZ) and tetrakis(4-N-methylpyridinumyl)porphyrin tetratosylate (TMPyP-Tos). The 4:3 adduct 4M·3TPTZ was obtained under solvent-free conditions and the 3:1 adduct 3M·TMPyP-Tos·9H2O in aqueous solution. In both adduct phases N-heterocycles are arranged in π–π stacks and melamine molecules are arranged perpendicular to these stacks. Whereas cohesion between the extended π-systems of N-heterocycles is mainly achieved by dispersive interactions no stacking interactions between melamine molecules occur. Melamine units are orientated in such a way to be located most suitable as donors and acceptors, respectively, for a dense hydrogen bonding network. In 4M·3TPTZ all molecules are involved in hydrogen bonding, whereas in 3M·TMPyP-Tos·9H2O hydrogen bridges are primarily formed between melamine, tosylate and water units and the macrocycle TMPyP is mainly bound by electrostatic interactions." @default.
- W1990023478 created "2016-06-24" @default.
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- W1990023478 date "2012-04-01" @default.
- W1990023478 modified "2023-09-25" @default.
- W1990023478 title "Supramolecular hydrogen-bonded structures between melamine and N-heterocycles" @default.
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- W1990023478 doi "https://doi.org/10.1016/j.molstruc.2012.01.010" @default.
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