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- W1990046260 abstract "The structure of the title compound, Na2[Cu(CHO2)3.72(C2H3O2)0.28], is built of sodium cations and CuII complex anions; the latter are linked into infinite chains. The CuII atoms are coordinated by five O atoms belonging to five formate ligands, forming a distorted square-pyramidal coordination. Four symmetry-independent formate ligands are bonded to the Cu atom with Cu—O distances in the range 1.9370 (10)–1.9886 (8) Å. The fifth formate ligand, bonded to the CuII atom at a longer distance of 2.2889 (9) Å, forms a bridge to the neighbouring copper(II) ion which is symmetry-related to the original ion by a twofold screw axis. Thus, infinite chains are formed along the b axis. One of the terminal formate ligands is disordered; 28.4 (13)% of its sites are occupied by acetate, which was present in the starting material and was not completely displaced in the course of the reaction." @default.
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- W1990046260 date "2003-03-21" @default.
- W1990046260 modified "2023-09-23" @default.
- W1990046260 title "<i>catena</i>-Poly[disodium [[tris(formato-κ<i>O</i>)copper(II)]-μ<sub>2</sub>-formato-κ<sup>2</sup><i>O</i>:<i>O</i>′]], with partial substitution of formate by acetate, Na<sub>2<i>n</i></sub>[Cu(O<sub>2</sub>CH)<sub>4−<i>x</i></sub>(O<sub>2</sub>CCH<sub>3</sub>)<sub><i>x</i></sub>]<sub><i>n</i></sub>(<i>x</i>= 0.28)" @default.
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- W1990046260 doi "https://doi.org/10.1107/s1600536803005567" @default.
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