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- W1990056617 abstract "The early electronic energy band model of carbon, as proposed in 1950, and its later modifications such as faster collapse of energy gap and the presence of band overlap in graphites are recalled to introduce the main topic of the paper. The problem of the band structure in the range between the collapse of the energy gap and the development of the overlap, that is for fine crystalline turbostratic and for disordered structures, was in recent years attacked in our laboratory by four different experimental techniques. Two of these turned out to furnish interesting results, which unfortunately, cannot yet be related to the band structure. However, the two other techniques, the electron spin resonance and the Hall coefficient studies, have yielded definite and concordant information: starting from well graphitized material as the disorder increases the overlap decreases at first, but after passing through a minimum it starts to increase again. The possible sources of such overlap and the general requirements for a band theory of disordered structures are discussed. Two additional new results, namely, the absence of the Hall minimum at HTT 1650° for the soft Kendall coke, and the reversal in the effect of boronation and of H2SO4 doping below HTT 1850°C, are mentioned." @default.
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- W1990056617 date "1971-03-01" @default.
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- W1990056617 title "Electronic properties and band model of carbons" @default.
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- W1990056617 doi "https://doi.org/10.1016/0008-6223(71)90123-0" @default.
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