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• W1990085223 startingPage "263" @default.
• W1990085223 abstract "This chapter discusses the activation of dioxygen by the cobalt-group metal complexes. The activation of dioxygen by transition metal complexes may appear at first to be both oxymoronic and redundant; common sense describes dioxygen as a powerful oxidant and a reactive species. Dioxygen could overcome the kinetic barrier of its unpaired electrons and triplet ground state by excitation to its first excited state, in which all electrons are paired. However, dioxygen complexation to a transition metal can also result in activation and create stable complexes that can be studied, modified, and used in further reactions in a controlled manner. The activation of dioxygen encompasses a broad spectrum of research fields, from biology/biochemistry to chemistry, and hence to catalysis, industrial processes, and theoretical analyses. Although a wide variety of nitrogen donor ligands exist in transitionmetal complexes, relatively few general types have been employed in those complexes that have been found to activate dioxygen." @default.
• W1990085223 created "2016-06-24" @default.
• W1990085223 creator A5044685979 @default.
• W1990085223 creator A5083642835 @default.
• W1990085223 date "1996-01-01" @default.
• W1990085223 modified "2023-10-16" @default.
• W1990085223 title "Activation of Dioxygen by Cobalt Group Metal Complexes" @default.
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