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- W1990086523 abstract "The title complex, (C26H21NP)2[Ni(C4N2S2)2], is a salt of the mCNBzTPP+cation and the [Ni(mnt)2]2− anion [mCNBzTPP+ is the 1-(3-cyanobenzyltriphenylphosphonium) cation and mnt2− is the maleonitriledithiolate anion] and was prepared by the direct reaction of NiCl2, Na2mnt and (mCNBzTPP)+·Br− in ethanol. The asymmetric unit consists of two unique mCNBzTPP+cations and half each of two [Ni(mnt)2]2− anions with each Ni atom lying on an inversion centre. The NiII ions adopt a square-planar coordination geometry, binding to the S atoms of two mnt2− ligands. Both [mCNBzTPP]+ cations adopt conformations in which their four aromatic rings are twisted with respect to the planes that include the P atoms and the two C atoms linking them to the 3-cyanobenzyl rings. Three weak C—H⋯N hydrogen bonds play an important role in stabilizing the crystal structure." @default.
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- W1990086523 date "2007-11-07" @default.
- W1990086523 modified "2023-09-27" @default.
- W1990086523 title "Bis[1-(3-cyanobenzyl)triphenylphosphonium] bis(1,2-dicyanoethene-1,2-dithiolato-κ<sup>2</sup><i>S</i>,<i>S</i>′)nickelate(II)" @default.
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- W1990086523 doi "https://doi.org/10.1107/s160053680705430x" @default.
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