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- W1990149315 abstract "2,5-Dideoxy-2,5-imino-D-glucitol (DGDP) has been synthesized via the tin(II)-mediated anti-selective aldol reaction of bislactim ether 5 and a 3-O-silylated 2,4-ethylidene-D-erythrose derivative 6. In accordance with density functional theory calculations (at the B3LYP/cc-pVDZ-PP level), pericyclic transition structures with a boat-like conformation and a stabilizing hydrogen bond can account for the unexpected stereoselectivity." @default.
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- W1990149315 date "2008-01-01" @default.
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- W1990149315 title "Access to pyrrolidine imino sugars via tin(ii)-mediated aldol reactions of bislactim ethers: synthesis of 2,5-dideoxy-2,5-imino-d-glucitol" @default.
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- W1990149315 doi "https://doi.org/10.1039/b810878a" @default.
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