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- W1990175666 abstract "Abstract The reaction of Y 2 O 3 and Li 2 CO 3 with NH 4 F to produce LiYF 4 was studied by thermogravimetric and X-ray diffraction methods. NH 4 F reacts easily with Li 2 CO 3 in a one-step exothermic process. Fluorination of yttrium oxide gives first YF 3 ·1.5NH 3 which which decomposes at 300–380°C to YF 3 + NH 3 . This process is exothermic. In the absence of excess NH 4 F, an amount of YOF is produced, in addition to YF 3 , as a product of the reaction of YF 3 and unreacted Y 2 O 3 . This reaction is endothermic. In the ternary system NH 4 FLi 2 CO 3 Y 2 O 3 , the first reacts separately with each of the other two and the resulting mixture of simple yttrium and lithium fluorides is converted into LiYF 4 at high temperatures." @default.
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- W1990175666 date "1995-11-01" @default.
- W1990175666 modified "2023-09-26" @default.
- W1990175666 title "Studies on the reaction of ammonium fluoride with lithium carbonate and yttrium oxide" @default.
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- W1990175666 doi "https://doi.org/10.1016/0040-6031(95)02426-3" @default.
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