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• W1990210880 abstract "Coordination and solvation structures of the Cu+(H2O)n ions with n = 1–4 are studied by infrared photodissociation spectroscopy and density functional theory calculations. Hydrogen-bonding between H2O molecules is detected in Cu+(H2O)3 and Cu+(H2O)4 through a characteristic change in the position and intensity of OH-stretching transitions. The third and fourth waters prefer hydrogen-bonding sites in the second solvation shell rather than direct coordination to Cu+. The infrared spectroscopy verifies that the gas-phase coordination number of Cu+ in Cu+(H2O)n is two and the resulting linearly coordinated structure acts as the core of further solvation processes." @default.
• W1990210880 created "2016-06-24" @default.
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• W1990210880 date "2006-08-01" @default.
• W1990210880 modified "2023-09-28" @default.
• W1990210880 title "Infrared photodissociation spectra and solvation structures of Cu+(H2O) (n= 1–4)" @default.
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• W1990210880 doi "https://doi.org/10.1016/j.cplett.2006.06.036" @default.
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