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- W1990227130 abstract "This work demonstrates a simple method to develop highly conducting high impact polystyrene (HIPS)/multi- wall carbon nanotube (MWCNT) nanocomposites through selective dispersion of MWCNT in HIPS matrix. The method involves in-situ polymerization of polybutadiene containing styrene monomer in the presence of HIPS beads and MWCNT. A significantly lower percolation threshold value than ever reported for HIPS/MWCNT systems was obtained using unmodified unaligned MWCNTs. With the increase in HIPS bead content (at a particular MWCNT loading) in the HIPS/MWCNT nanocomposites, the conductivity value was increased, suggesting that the presence of HIPS beads acted as excluded volume that decreased the percolation threshold. An increase in electrical conductivity from 1.91·10 -7 to 1.15·10 -5 S/cm was evident, when the HIPS bead content was increased from 30 to 60 wt% at a constant loading of MWCNT (i.e. 0.6 wt%). The morphological investigation of the HIPS/MWCNT nanocomposites revealed that, the MWC- NTs were selectively dispersed in the in-situ polymerized HIPS region, outside the HIPS beads, which resulted in the low- ering of the percolation threshold to a lower value of 0.54 wt%. The morphology and electrical properties of the nanocomposites have been discussed in detail in the manuscript." @default.
- W1990227130 created "2016-06-24" @default.
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- W1990227130 date "2014-01-01" @default.
- W1990227130 modified "2023-10-17" @default.
- W1990227130 title "Influence of selective dispersion of MWCNT on electrical percolation of in-situ polymerized high-impact polystyrene/MWCNT nanocomposites" @default.
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- W1990227130 doi "https://doi.org/10.3144/expresspolymlett.2014.3" @default.
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