FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1990233438> ?p ?o ?g. }

• W1990233438 endingPage "3003" @default.
• W1990233438 startingPage "2997" @default.
• W1990233438 abstract "Chloroperoxidase is a versatile fungal heme-thiolate protein that catalyzes a variety of one-electron and two-electron oxidations. We report here that the alkylation of an essential histidine residue showed no effect on the one-electron peroxidations but inhibited two-electron oxidations. The pH profiles of different peroxidative substrates showed optimal activities at varying pH values for the same enzyme. 2-Allylphenol and substituted ortho-phenolics showed efficient peroxidations. Also, substrates excluded from the active site (or with no favorable positioning at the heme center or heme edge) were converted in the peroxidation reaction. While hydrogen peroxide serves as the superior activator in the two-electron oxidations, small alkylhydroperoxides give much better rates for peroxidation reactions. All the above observations indicate that one-electron oxidations are mechanistically quite different from the two-electron oxidations catalyzed by chloroperoxidase. We propose that the peroxidatic substrates interact predominantly outside the heme active site, presumably at the surface of the enzyme." @default.
• W1990233438 created "2016-06-24" @default.
• W1990233438 creator A5062465747 @default.
• W1990233438 creator A5063916487 @default.
• W1990233438 date "2008-01-26" @default.
• W1990233438 modified "2023-09-27" @default.
• W1990233438 title "Chloroperoxidase, a Janus Enzyme" @default.
• W1990233438 cites W1512862543 @default.
• W1990233438 cites W1528896959 @default.
• W1990233438 cites W1550488132 @default.
• W1990233438 cites W1552275849 @default.
• W1990233438 cites W1564101110 @default.
• W1990233438 cites W1588744566 @default.
• W1990233438 cites W1590377765 @default.
• W1990233438 cites W1633072172 @default.
• W1990233438 cites W1803620352 @default.
• W1990233438 cites W1848234215 @default.
• W1990233438 cites W1965026075 @default.
• W1990233438 cites W1966211280 @default.
• W1990233438 cites W1979140137 @default.
• W1990233438 cites W1982197350 @default.
• W1990233438 cites W1982542467 @default.
• W1990233438 cites W1991658710 @default.
• W1990233438 cites W1991998605 @default.
• W1990233438 cites W1995134955 @default.
• W1990233438 cites W2002142104 @default.
• W1990233438 cites W2002256184 @default.
• W1990233438 cites W2017814432 @default.
• W1990233438 cites W2026564861 @default.
• W1990233438 cites W2026662914 @default.
• W1990233438 cites W2033449687 @default.
• W1990233438 cites W2037353343 @default.
• W1990233438 cites W203985431 @default.
• W1990233438 cites W2047127379 @default.
• W1990233438 cites W2058332165 @default.
• W1990233438 cites W2070247886 @default.
• W1990233438 cites W2071791509 @default.
• W1990233438 cites W2087196622 @default.
• W1990233438 cites W2108865938 @default.
• W1990233438 cites W2124124969 @default.
• W1990233438 cites W2170078156 @default.
• W1990233438 cites W2949124924 @default.
• W1990233438 cites W2951105362 @default.
• W1990233438 cites W2951164146 @default.
• W1990233438 doi "https://doi.org/10.1021/bi7022656" @default.
• W1990233438 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18220360" @default.
• W1990233438 hasPublicationYear "2008" @default.
• W1990233438 type Work @default.
• W1990233438 sameAs 1990233438 @default.
• W1990233438 citedByCount "90" @default.
• W1990233438 countsByYear W19902334382012 @default.
• W1990233438 countsByYear W19902334382013 @default.
• W1990233438 countsByYear W19902334382014 @default.
• W1990233438 countsByYear W19902334382015 @default.
• W1990233438 countsByYear W19902334382016 @default.
• W1990233438 countsByYear W19902334382017 @default.
• W1990233438 countsByYear W19902334382018 @default.
• W1990233438 countsByYear W19902334382019 @default.
• W1990233438 countsByYear W19902334382020 @default.
• W1990233438 countsByYear W19902334382021 @default.
• W1990233438 countsByYear W19902334382022 @default.
• W1990233438 countsByYear W19902334382023 @default.
• W1990233438 crossrefType "journal-article" @default.
• W1990233438 hasAuthorship W1990233438A5062465747 @default.
• W1990233438 hasAuthorship W1990233438A5063916487 @default.
• W1990233438 hasConcept C181199279 @default.
• W1990233438 hasConcept C185592680 @default.
• W1990233438 hasConcept C20705724 @default.
• W1990233438 hasConcept C21951064 @default.
• W1990233438 hasConcept C2776217839 @default.
• W1990233438 hasConcept C2777723881 @default.
• W1990233438 hasConcept C2778460671 @default.
• W1990233438 hasConcept C2781338088 @default.
• W1990233438 hasConcept C41183919 @default.
• W1990233438 hasConcept C533411734 @default.
• W1990233438 hasConcept C55493867 @default.
• W1990233438 hasConcept C71240020 @default.
• W1990233438 hasConcept C75473681 @default.
• W1990233438 hasConceptScore W1990233438C181199279 @default.
• W1990233438 hasConceptScore W1990233438C185592680 @default.
• W1990233438 hasConceptScore W1990233438C20705724 @default.
• W1990233438 hasConceptScore W1990233438C21951064 @default.
• W1990233438 hasConceptScore W1990233438C2776217839 @default.
• W1990233438 hasConceptScore W1990233438C2777723881 @default.
• W1990233438 hasConceptScore W1990233438C2778460671 @default.
• W1990233438 hasConceptScore W1990233438C2781338088 @default.
• W1990233438 hasConceptScore W1990233438C41183919 @default.
• W1990233438 hasConceptScore W1990233438C533411734 @default.
• W1990233438 hasConceptScore W1990233438C55493867 @default.
• W1990233438 hasConceptScore W1990233438C71240020 @default.
• W1990233438 hasConceptScore W1990233438C75473681 @default.
• W1990233438 hasIssue "9" @default.
• W1990233438 hasLocation W19902334381 @default.
• W1990233438 hasLocation W19902334382 @default.
• W1990233438 hasOpenAccess W1990233438 @default.
• W1990233438 hasPrimaryLocation W19902334381 @default.
• W1990233438 hasRelatedWork W1508245565 @default.
• W1990233438 hasRelatedWork W1564710677 @default.

• next