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- W1990255655 abstract "Abstract A highly versatile approach to fabricate functional gold nanoparticle (AuNP)‐polymer hybrids is demonstrated by employing sulfonated block copolymers. The 3–5 nm sized ionic domain of the sulfonated poly(styrene‐ block ‐methylbutylene) (S n MB m ) copolymers can be utilized as a nanoreactor where the Au ions can be selectively sequestered and reduced to AuNPs using a simple photochemical method. The size of the AuNPs can be adjusted in fine‐steps from 2.0 ± 0.3 to 3.9 ± 0.5 nm by changing the sulfonation levels of the S n MB m copolymers. Remarkably, significantly improved methanol oxidation properties are achieved with the hybrid materials owing to the ion conducting–SO 3 H groups and the interconnected network of AuNPs confined within the self‐assembled microstructures, which provides electronic conductivity." @default.
- W1990255655 created "2016-06-24" @default.
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- W1990255655 date "2011-09-14" @default.
- W1990255655 modified "2023-10-16" @default.
- W1990255655 title "Facile One-Pot Synthesis of Functional Gold Nanoparticle-Polymer Hybrids Using Ionic Block Copolymers as a Nanoreactor" @default.
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- W1990255655 doi "https://doi.org/10.1002/marc.201100449" @default.
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