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- W1990297218 abstract "Die durch Röntgenstrahlen erzeugten stabilen Radikale in Einkristallen des 2,6-Butylhydroxytoluols (BHT) geben bei Messungen der Elektronenspinresonanz eine aus vier Linien bestehende Hyperfeinstruktur mit dem Intensitätsverhältnis 1:3:3:1. Sie stammt von der Wechselwirkung des ungepaarten Elektrons des Semichinonradikals des BHT mit drei Protonen der Methylgruppe. Der fehlende anisotrope Anteil der Wechselwirkung spricht für die Rotation der Methylgruppe im Festkörper. Die Spindichten des BHT-Radikals wurden nach dem MO-SCF-Verfahren nach McLachlan berechnet und mit den experimentell gewonnenen Spindichten verglichen. Electron-paramagnetic resonance of stable radicals, obtained by X-ray irradiation of 2,6-butylhydroxytoluene (BHT) single crystals shows a hyperfine structure of four lines with the intensity ratio 1:3:3:1. This is due to the interaction of the unpaired electrons of the semi-chinon radical of BHT with three protons of the methyl group. The absence of an anisotropic component in the interaction may be originate from the rotation of the methyl group in the solid. The spin-densities of the radical are calculated using the MO-SCF method of McLachlan and compared with experimental data." @default.
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- W1990297218 date "1966-01-01" @default.
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- W1990297218 title "Die Elektronenspinresonanz von strahlenerzeugten Radikalen in Einkristallen des 2,6-Butylhydroxytoluols" @default.
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- W1990297218 doi "https://doi.org/10.1002/pssb.19660170224" @default.
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