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- W1990322564 abstract "The oxidation of phenolic substrates with H2O2 catalysed by [MnIV2(μ-O)3(TMTACN)2](PF6)21, (TMTACN, 1,4,7-trimethyl-1,4,7-triazacyclononane) has been investigated by use of ESI mass spectrometry. The role of the phenols as one-electron reductants and as co-ligands in the stabilisation and reaction of an intermediate OMnV species has been analysed and the presence of a variety of manganese species in solution has been explained. Our results lead to a proposed mechanism for the catalytic oxidation of phenols in this system." @default.
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- W1990322564 date "2004-01-01" @default.
- W1990322564 modified "2023-09-27" @default.
- W1990322564 title "Formation and reaction of OMn<sup>V</sup>species in the oxidation of phenolic substrates with H<sub>2</sub>O<sub>2</sub>catalysed by the dinuclear manganese(<scp>iv</scp>) 1,4,7-trimethyl-1,4,7-triazacyclononane complex [Mn<sup>IV</sup><sub>2</sub>(μ-O)<sub>3</sub>(TMTACN)<sub>2</sub>](PF<sub>6</sub>)<sub>2</sub>" @default.
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- W1990322564 doi "https://doi.org/10.1039/b315427k" @default.
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