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• W1990336871 abstract "Derivatives of the Tröger base are finding increasing application in supramolecular chemistry: they are introduced as rigid scaffolds into synthetic receptors and ‘molecular torsional balances’ to quantify weak intermolecular interactions, and serve as efficient ‘covalent templates’ in the tether-directed remote functionalization of fullerenes. This paper describes the facile synthesis of symmetrically (Schemes 1 and 2) and unsymmetrically (Schemes 4 and 5) substituted Tröger base derivatives starting from the corresponding, readily available dihalo compounds. A variety of metal-catalyzed cross-coupling reactions, including Suzuki couplings, palladium-catalyzed cyanation and boronation, and copper-catalyzed amidations are used to achieve these transformations." @default.
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• W1990336871 date "2005-08-01" @default.
• W1990336871 modified "2023-10-14" @default.
• W1990336871 title "Preparation ofTröger Base Derivatives by Cross-Coupling Methodologies" @default.
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• W1990336871 doi "https://doi.org/10.1002/hlca.200590168" @default.
• W1990336871 hasPublicationYear "2005" @default.
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