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- W1990341201 abstract "The electronic Raman transitions of atomic bromine between the 2P1/2 and 2P3/2 states have been observed at 3685 cm−1 using excitation with 4880 Å radiation from an argon ion laser. The intensities of the Raman bands in the Stokes and anti-Stokes sides were studied by varying the laser power and the pressure of Br2. A mechanism or photodissociation process for the production of these atoms by the intense laser radiation is proposed. The crossing between the potential curves of the B3π and 1π states could be important in reducing the population of Br* in the 2P1/2 excited state, and therefore the intensity of the observed Raman band at the anti-Stokes side was only about 1% of the intensity of the Stokes band. This would be a good method for studying photodissociation by means of Raman scattering from the dissociation products excited by the same laser radiation." @default.
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- W1990341201 date "1986-12-01" @default.
- W1990341201 modified "2023-09-27" @default.
- W1990341201 title "Photodissociation of Br2 and the electronic Raman spectra of Br under argon ion laser light" @default.
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- W1990341201 doi "https://doi.org/10.1002/jrs.1250170605" @default.
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