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- W1990350487 abstract "An investigation of the kinetics of the oxidation of gaseous acetylene has been made by the static method. The results show marked irregularities due to variations in the surface. The rate of the reaction is given by −(d/dt)(C2H2)=K(C2H2)2.7/(O2)0·1 when oxygen is in excess. In a packed bulb the order is diminished to about 1.4. Packing decreases the rate at high pressures and has little effect at low pressures. In an empty vessel the CO/CO2 ratio of the products is independent of the pressure. Packing decreases this ratio, and it further decreases rapidly with diminishing pressure. The apparent heat of activation of the reaction is about 35,000 calories. The addition of glyoxal to the reaction mixture causes no change in the rate of the reaction, while formaldehyde causes a marked retardation. The products of the reaction are discussed in the light of recent work on the oxidation and decomposition of glyoxal." @default.
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- W1990350487 date "1936-01-01" @default.
- W1990350487 modified "2023-09-24" @default.
- W1990350487 title "The Kinetics of the Oxidation of Gaseous Hydrocarbons III. The Oxidation of Acetylene" @default.
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- W1990350487 doi "https://doi.org/10.1063/1.1749751" @default.
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