FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1990374109> ?p ?o ?g. }

• W1990374109 endingPage "257" @default.
• W1990374109 startingPage "225" @default.
• W1990374109 abstract "Quantitative characterization of the development of proton surface charge on the surfaces of minerals is necessary for a fundamental understanding of reactions between minerals and aqueous electrolyte solutions. Despite many experimental studies of charge development, few attempts have been made to integrate the results of such studies with a theoretical framework that permits prediction. The present study builds on a theoretical framework to analyze a total of 55 sets of proton surface charge data referring to wide ranges of ionic strengths, and types of electrolyte and oxide. The resulting parameters were interpreted with the aid of crystal chemical, electrostatic, and thermodynamic theory, which enable a number of generalizations. Prediction of values of the pH ZPC and Δ pK n θ reduces the number of triple-layer parameters to be estimated. New standard states for the equilibrium constants for electrolyte adsorption ( K M + θ and K L − θ ) permit direct comparison of samples with a range of surface areas or site densities. Predicted cation binding on high dielectric constant solids (e.g., rutile) shows K M + θ , increasing in the sequence Cs + , Rb + , K + , Na + , Li + . In contrast, on low dielectric constant solids (e.g., amorphous silica), the predicted sequence is Li + , Na + , K + , Rb + , Cs + . The opposite sequences are attributable to the large solvation energy contribution opposing adsorption on low-dielectric constant solids. Cation and anion binding constants are in general different, which enables direct prediction of the point-of-zero-salt effect ( pH PZSE ) relative to the pristine point-of-zero charge. The inner and outer capacitances in the triple-layer model ( C 1 and C 2 ) are predictable parameters consistent with physically reasonable distances and interfacial dielectric constants for water. In summary, all the parameters in the triple-layer model can be estimated with the revised equations of this study, which enables prediction of proton surface charge for any oxide in 1:1 electrolyte solutions independent of experiments. Such predictions can serve as a complement to the experimental study of new oxide/electrolyte systems, or more complex systems, where additional mechanisms of charge development are likely." @default.
• W1990374109 created "2016-06-24" @default.
• W1990374109 creator A5071306738 @default.
• W1990374109 date "2005-01-01" @default.
• W1990374109 modified "2023-09-29" @default.
• W1990374109 title "Prediction of surface charge on oxides in salt solutions: Revisions for 1:1 (M+L−) electrolytes" @default.
• W1990374109 cites W1496565090 @default.
• W1990374109 cites W1506079020 @default.
• W1990374109 cites W1512695912 @default.
• W1990374109 cites W1531966272 @default.
• W1990374109 cites W1963554005 @default.
• W1990374109 cites W1964050329 @default.
• W1990374109 cites W1964347147 @default.
• W1990374109 cites W1964417493 @default.
• W1990374109 cites W1966491537 @default.
• W1990374109 cites W1968730317 @default.
• W1990374109 cites W1969051824 @default.
• W1990374109 cites W1970721850 @default.
• W1990374109 cites W1973475165 @default.
• W1990374109 cites W1974110701 @default.
• W1990374109 cites W1979093248 @default.
• W1990374109 cites W1979389443 @default.
• W1990374109 cites W1983312523 @default.
• W1990374109 cites W1987665848 @default.
• W1990374109 cites W1990269711 @default.
• W1990374109 cites W1990407093 @default.
• W1990374109 cites W1992432653 @default.
• W1990374109 cites W1995080285 @default.
• W1990374109 cites W1999869944 @default.
• W1990374109 cites W2000677233 @default.
• W1990374109 cites W2004200788 @default.
• W1990374109 cites W2014365296 @default.
• W1990374109 cites W2014416110 @default.
• W1990374109 cites W2016580286 @default.
• W1990374109 cites W2016992496 @default.
• W1990374109 cites W2025994710 @default.
• W1990374109 cites W2026155926 @default.
• W1990374109 cites W2028020885 @default.
• W1990374109 cites W2030174795 @default.
• W1990374109 cites W2030730997 @default.
• W1990374109 cites W2033230271 @default.
• W1990374109 cites W2034331981 @default.
• W1990374109 cites W2035003890 @default.
• W1990374109 cites W2036122636 @default.
• W1990374109 cites W2036666232 @default.
• W1990374109 cites W2036963891 @default.
• W1990374109 cites W2037759721 @default.
• W1990374109 cites W2038291938 @default.
• W1990374109 cites W2040866285 @default.
• W1990374109 cites W2041862179 @default.
• W1990374109 cites W2044281222 @default.
• W1990374109 cites W2044561123 @default.
• W1990374109 cites W2044905098 @default.
• W1990374109 cites W2045807854 @default.
• W1990374109 cites W2047394098 @default.
• W1990374109 cites W2053450794 @default.
• W1990374109 cites W2060712500 @default.
• W1990374109 cites W2062346731 @default.
• W1990374109 cites W2065576355 @default.
• W1990374109 cites W2066236825 @default.
• W1990374109 cites W2066527077 @default.
• W1990374109 cites W2069770779 @default.
• W1990374109 cites W2074571150 @default.
• W1990374109 cites W2074729445 @default.
• W1990374109 cites W2076505376 @default.
• W1990374109 cites W2078616161 @default.
• W1990374109 cites W2079755697 @default.
• W1990374109 cites W2082547953 @default.
• W1990374109 cites W2087041232 @default.
• W1990374109 cites W2088852252 @default.
• W1990374109 cites W2089139031 @default.
• W1990374109 cites W2089588915 @default.
• W1990374109 cites W2090543559 @default.
• W1990374109 cites W2091558236 @default.
• W1990374109 cites W2092482146 @default.
• W1990374109 cites W2093767093 @default.
• W1990374109 cites W2094343018 @default.
• W1990374109 cites W2095627043 @default.
• W1990374109 cites W2097567219 @default.
• W1990374109 cites W2101494593 @default.
• W1990374109 cites W2109457937 @default.
• W1990374109 cites W2114188128 @default.
• W1990374109 cites W2119842274 @default.
• W1990374109 cites W2119894260 @default.
• W1990374109 cites W2133476129 @default.
• W1990374109 cites W2138837370 @default.
• W1990374109 cites W2146202933 @default.
• W1990374109 cites W2158939753 @default.
• W1990374109 cites W2161814610 @default.
• W1990374109 cites W2166072404 @default.
• W1990374109 cites W2169641210 @default.
• W1990374109 cites W2169670761 @default.
• W1990374109 cites W2171177132 @default.
• W1990374109 cites W2316631046 @default.
• W1990374109 cites W2323493158 @default.
• W1990374109 cites W2323882202 @default.
• W1990374109 cites W2518235100 @default.
• W1990374109 cites W2752907953 @default.

• next