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- W1990383267 abstract "Binuclear derivatives [M(μ-L)(C6X5)2]2 (M=Pd, Pt; X=F, Cl; L=ONC5H4OMe-p, SC4H8, SMe2, SPPh3) are obtained by reacting cis-M(C6X5)2(OC4H8)2 with the corresponding ligands L (molar ratio 1:1). When the reactions are carried out in a 1:2 molar ratio the mononuclear derivatives cis- M(C6X5)2L2 (M=Pd, Pt; X=F, Cl; L=OPPh3, ONC5H4OMe-p, SC4H8, SMe2) are obtained. For L=OPPh3 only the mononuclear complexes are isolated, while the binuclear derivatives are obtained when L = SPPh3 for any molar ratio used. The binuclear derivatives can also be obtained by reacting cis-M(C6X5)2L2 with cis-M(C6X5)2(OC4H8)2 (molar ratio 1:1). The structures of these complexes are discussed on the basis of IR, 1H and 19F NMR data." @default.
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- W1990383267 date "1989-08-01" @default.
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- W1990383267 title "Synthesis of mononuclear cis-M(C6X5)2L2 or binuclear [M(μ-L)(C6X5)2]2 complexes (M = Pd, Pt; X = F, Cl) containing neutral O- or S-donor ligands L" @default.
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- W1990383267 doi "https://doi.org/10.1016/s0020-1693(00)83116-3" @default.
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