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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1990384290> ?p ?o ?g. }

• W1990384290 abstract "An experimental approach to the verification of specific relations between thermodynamic properties as predicted from the Griffiths-Wheeler theory of critical phenomena in multicomponent systems is developed for the particular case of ordinary liquid-liquid critical points of binary mixtures. Densities $ensuremath{rho}(T)$, isobaric heat capacities per unit volume ${C}_{p}(T)$, and previously reported values of the slope of the critical line ${(dT∕dp)}_{c}$ for five critical mixtures are used to check the thermodynamic consistency of ${C}_{p}$ and $ensuremath{rho}$ near the critical point. An appropriate treatment of $ensuremath{rho}(T)$ data is found to provide the key solution to this issue. In addition, various alternative treatments for ${C}_{p}(T)$ data provide values for both the critical exponent $ensuremath{alpha}$ and the ratio between the critical amplitudes of the heat capacity ${A}^{+}∕{A}^{ensuremath{-}}$ that are in agreement with their widely accepted counterparts, whereas two-scale-factor universality is successfully verified in one of the systems studied." @default.
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• W1990384290 date "2005-02-24" @default.
• W1990384290 modified "2023-09-24" @default.
• W1990384290 title "Griffiths-Wheeler geometrical picture of critical phenomena: Experimental testing for liquid-liquid critical points" @default.
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• W1990384290 doi "https://doi.org/10.1103/physreve.71.021503" @default.
• W1990384290 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15783329" @default.
• W1990384290 hasPublicationYear "2005" @default.
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