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• W1990396044 endingPage "3840" @default.
• W1990396044 startingPage "3831" @default.
• W1990396044 abstract "The syntheses of the alkylidyne complexes [W(⋮CR)(CO)2{HB(mt)3}] (R = NiPr2 1a, C4H3S-2 1b, C⋮CCMe3 1c, C6H4Me-4 1d, C6H3Me2-2,6 1e, C5H4Mn(CO)3 1f; mt = 2-mercapto-3-methylimidazolyl) are reported. The crystal structures of three examples (1a, 1b, and 1c) reveal a progressive distortion of the alkylidyne ligand from octahedral coordination at tungsten, and in addition have a chiral C3-symmetric conformation for the B(mt)3W cage, which is also implicit from solution NMR data. A set of parameters is suggested for describing the geometry of HB(mt)3M cages." @default.
• W1990396044 created "2016-06-24" @default.
• W1990396044 creator A5044555559 @default.
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• W1990396044 creator A5091826237 @default.
• W1990396044 date "2003-08-16" @default.
• W1990396044 modified "2023-09-25" @default.
• W1990396044 title "Hydrotris(methimazolyl)borato Alkylidyne Complexes of Tungsten¹" @default.
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• W1990396044 doi "https://doi.org/10.1021/om030288b" @default.
• W1990396044 hasPublicationYear "2003" @default.
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