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- W1990405557 abstract "Treatment of MoCl(3)(thf)(3) with LiSC(6)H(3)-2,6-(SiMe(3))(2) (LiSAr) resulted in formation of the pi-sandwiched bis-arylthiolato complex, Mo(eta(5)-SC(6)H(3)-2,6-(SiMe(3))(2))(eta(7)-SC(6)H(3)-2,6-(SiMe(3))(2)) (1), while the analogous reaction with LiSC(6)H(3)-2-Ph-6-SiMe(3) afforded the trithiolate complex Mo(SC(6)H(3)-2-Ph-6-SiMe(3))(3) (3). The acetonitrile adduct Mo(SAr)(2)(CH(3)CN)(3) (2) was isolated from the CH(3)CN solution of 1, in which one acetonitrile is coordinated to the metal center in an eta(2)-fashion. Structures of 1, 2, and 3 have been determined by X-ray diffraction." @default.
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- W1990405557 date "2003-02-01" @default.
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- W1990405557 title "Unusual Coordination Modes of Arylthiolates in Mo{η<sup>5</sup>-SC<sub>6</sub>H<sub>3</sub>-2,6-(SiMe<sub>3</sub>)<sub>2</sub>}{η<sup>7</sup>-SC<sub>6</sub>H<sub>3</sub>-2,6-(SiMe<sub>3</sub>)<sub>2</sub>}" @default.
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- W1990405557 doi "https://doi.org/10.1021/ja029541+" @default.
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