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• W1990449849 abstract "Transmission of vibrational excitation energy conserved in cis-conformation of retinal to the outlet proton channel is considered from the perspective of quantum theory. A distribution of vibrational excitations in the channel is found; it allowed to calculate the magnitude of the directed drift proton current. The differences between velocities of proton movement in active and passive channels are considered. A transition of retinal from cis- to all -trans- conformation with the subsequent capture of proton by Schiff base out of the inlet channel is described. The lack of proton in this channel, i.e., in the H-bonded chain, is eliminated at the expense of the capture of a proton out of the cytoplasmic water enviroment. The correspondence between theoretically established states and spectroscopically identified forms of bacteriorhodopsin (inter-mediates L, M, N, and O) is proposed." @default.
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• W1990449849 date "1988-04-01" @default.
• W1990449849 modified "2023-09-24" @default.
• W1990449849 title "The mechanism of bacteriorhodopsin functioning. II. Ejection and injection of proton" @default.
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• W1990449849 doi "https://doi.org/10.1002/qua.560330409" @default.
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