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• W1990457071 abstract "A highly selective method for the determination of hydrogen peroxide is presented. In a flow injection analysis (FIA) instrument, the analyte is brought into contact with a dinuclear heptadentate iron(III) complex. The formation of the peroxide adduct is quantified using electrospray tandem mass spectrometry (ESI-MS/MS). Selected reaction monitoring (SRM) based on the transition from the triply charged peroxide adduct with m/z = 251.2 to the triply charged fragment ion of m/z = 240.5 is performed. The limit of detection for hydrogen peroxide is 10(-7) mol dm(-3), limit of quantification is 3 x 10(-7) mol dm(-3), and a linear range of 2.5 decades starting at the limit of quantification is observed." @default.
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• W1990457071 date "2002-01-01" @default.
• W1990457071 modified "2023-10-11" @default.
• W1990457071 title "Selective determination of hydrogen peroxide by adduct formation with a dinuclear iron(<scp>iii</scp>) complex and flow injection analysis/tandem mass spectrometry" @default.
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• W1990457071 doi "https://doi.org/10.1039/b207637n" @default.
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