Matches in SemOpenAlex for { <https://semopenalex.org/work/W1990460610> ?p ?o ?g. }
- W1990460610 endingPage "168" @default.
- W1990460610 startingPage "161" @default.
- W1990460610 abstract "The phase transition observed by various methods in poly(vinyl methyl ether)/water systems at around 18 °C has been assigned by some investigators to the pre-melting of water and by others to a glass transition of the polymer. In this study, broadband dielectric spectroscopy and temperature modulated differential scanning calorimetry were used to identify this transition in radiationally crosslinked poly(vinyl methyl ether) hydrogels, as well as to analyse sub-zero relaxation processes in such a three-phase (polymer/ice/liquid water) system. The process at 18 °C was related to the pre-melting of water induced by the segmental motions of the polymer; however, it was seen to be one transition due to the cooperative motions of both compounds. The atypical (two regimes) temperature dependence of the segmental motion process was observed and was related to confinement of the polymer chains between ice clusters below approximately −24 °C; furthermore, the main dielectric process of hexagonal ice was identified and a Maxwell-Wagner effect was observed." @default.
- W1990460610 created "2016-06-24" @default.
- W1990460610 creator A5006094492 @default.
- W1990460610 creator A5012313701 @default.
- W1990460610 creator A5018077541 @default.
- W1990460610 creator A5028463043 @default.
- W1990460610 creator A5034834617 @default.
- W1990460610 creator A5034921203 @default.
- W1990460610 creator A5054493865 @default.
- W1990460610 creator A5060110923 @default.
- W1990460610 creator A5064194000 @default.
- W1990460610 creator A5067024070 @default.
- W1990460610 date "2012-01-01" @default.
- W1990460610 modified "2023-09-23" @default.
- W1990460610 title "Relaxation processes and intermolecular interactions in PVME hydrogels in sub-zero temperatures: Glass transition and pre-melting of ice" @default.
- W1990460610 cites W1967801277 @default.
- W1990460610 cites W1974688851 @default.
- W1990460610 cites W1982400649 @default.
- W1990460610 cites W1985414772 @default.
- W1990460610 cites W1985639203 @default.
- W1990460610 cites W1991066692 @default.
- W1990460610 cites W1993405403 @default.
- W1990460610 cites W1994625732 @default.
- W1990460610 cites W2003630933 @default.
- W1990460610 cites W2004675105 @default.
- W1990460610 cites W2005362467 @default.
- W1990460610 cites W2005557473 @default.
- W1990460610 cites W2013495332 @default.
- W1990460610 cites W2016848943 @default.
- W1990460610 cites W2026692006 @default.
- W1990460610 cites W2039986215 @default.
- W1990460610 cites W2041255519 @default.
- W1990460610 cites W2046092377 @default.
- W1990460610 cites W2057766665 @default.
- W1990460610 cites W2072060342 @default.
- W1990460610 cites W2078815155 @default.
- W1990460610 cites W2085712370 @default.
- W1990460610 cites W2092272681 @default.
- W1990460610 cites W2093343474 @default.
- W1990460610 cites W2109357036 @default.
- W1990460610 cites W2130454037 @default.
- W1990460610 cites W2134890493 @default.
- W1990460610 cites W2135344399 @default.
- W1990460610 cites W2166715179 @default.
- W1990460610 cites W1995877251 @default.
- W1990460610 doi "https://doi.org/10.1016/j.polymer.2011.11.030" @default.
- W1990460610 hasPublicationYear "2012" @default.
- W1990460610 type Work @default.
- W1990460610 sameAs 1990460610 @default.
- W1990460610 citedByCount "6" @default.
- W1990460610 countsByYear W19904606102014 @default.
- W1990460610 countsByYear W19904606102015 @default.
- W1990460610 countsByYear W19904606102017 @default.
- W1990460610 countsByYear W19904606102021 @default.
- W1990460610 crossrefType "journal-article" @default.
- W1990460610 hasAuthorship W1990460610A5006094492 @default.
- W1990460610 hasAuthorship W1990460610A5012313701 @default.
- W1990460610 hasAuthorship W1990460610A5018077541 @default.
- W1990460610 hasAuthorship W1990460610A5028463043 @default.
- W1990460610 hasAuthorship W1990460610A5034834617 @default.
- W1990460610 hasAuthorship W1990460610A5034921203 @default.
- W1990460610 hasAuthorship W1990460610A5054493865 @default.
- W1990460610 hasAuthorship W1990460610A5060110923 @default.
- W1990460610 hasAuthorship W1990460610A5064194000 @default.
- W1990460610 hasAuthorship W1990460610A5067024070 @default.
- W1990460610 hasConcept C121332964 @default.
- W1990460610 hasConcept C122865956 @default.
- W1990460610 hasConcept C133386390 @default.
- W1990460610 hasConcept C149288129 @default.
- W1990460610 hasConcept C15744967 @default.
- W1990460610 hasConcept C159467904 @default.
- W1990460610 hasConcept C159985019 @default.
- W1990460610 hasConcept C185592680 @default.
- W1990460610 hasConcept C188027245 @default.
- W1990460610 hasConcept C192562407 @default.
- W1990460610 hasConcept C2776029896 @default.
- W1990460610 hasConcept C39519442 @default.
- W1990460610 hasConcept C49040817 @default.
- W1990460610 hasConcept C521977710 @default.
- W1990460610 hasConcept C77805123 @default.
- W1990460610 hasConcept C97355855 @default.
- W1990460610 hasConceptScore W1990460610C121332964 @default.
- W1990460610 hasConceptScore W1990460610C122865956 @default.
- W1990460610 hasConceptScore W1990460610C133386390 @default.
- W1990460610 hasConceptScore W1990460610C149288129 @default.
- W1990460610 hasConceptScore W1990460610C15744967 @default.
- W1990460610 hasConceptScore W1990460610C159467904 @default.
- W1990460610 hasConceptScore W1990460610C159985019 @default.
- W1990460610 hasConceptScore W1990460610C185592680 @default.
- W1990460610 hasConceptScore W1990460610C188027245 @default.
- W1990460610 hasConceptScore W1990460610C192562407 @default.
- W1990460610 hasConceptScore W1990460610C2776029896 @default.
- W1990460610 hasConceptScore W1990460610C39519442 @default.
- W1990460610 hasConceptScore W1990460610C49040817 @default.
- W1990460610 hasConceptScore W1990460610C521977710 @default.
- W1990460610 hasConceptScore W1990460610C77805123 @default.
- W1990460610 hasConceptScore W1990460610C97355855 @default.
- W1990460610 hasIssue "1" @default.