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- W1990482933 abstract "Abstract Both second-order rate constants of SN2 reactions on benzyl bromide and p-nitrobenzyl bromide with hydroxy nucleophiles and those of the Michael addition reactions of a few amines to p-tolyl vinyl sulfone have been determined. The values of kHOO-/kHO- for benzyl and p-nitrobenzyl bromide were very small, i.e., 1.3 and 1.2 respectively; in the SN 2 reaction on sp3carbon this may be due to the lack of tight σ-bond formation at the transition state. A very small positive deviation from the Bronsted plots was observed in the Michael addition of hydrazine and other amines to p-tolyl vinyl sulfone. This may be due to the small β-value associated with the reaction." @default.
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- W1990482933 date "1997-04-01" @default.
- W1990482933 modified "2023-09-25" @default.
- W1990482933 title "LACK OF ENHANCed REACTIVITY OF α-NUCLEOPHILES In THE SN2 REACTIONS OF BENZYL BROMIDES AND SMALL α-EFFECT In THE MICHAEL ADDITION RECTION OF AMIDES TO P-TOLYL VINYL SULFONE" @default.
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- W1990482933 doi "https://doi.org/10.1080/10426509708044217" @default.
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