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• W1990487434 abstract "Tetragonal R1+εFe4B4 alloys with R = Gd and Dy have been investigated by Mössbauer spectroscopy, using the 155Gd and 161Dy resonances, respectively. The Gd quadrupolar interaction e2qQ = 12.65(5)mm/s is the largest observed to date in metallic compounds of Gd. For Dy this interaction is e2qQ = 74(2) mm/s, a value rather small for a Dy compound. Both results imply a strong lattice contribution to the electric field gradient. A crystal-field term A02 = -2450(50) K/a2o is inferred. Our data are consistent with a point-charge calculation, provided charges of opposite signs are assumed for Fe and B atoms. Hyperfine parameters show some dispersion, reflecting the quasi incommensurate nature of the R and Fe+B sublattices in the R1+εFe4B4 structure." @default.
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• W1990487434 date "1987-10-01" @default.
• W1990487434 modified "2023-10-08" @default.
• W1990487434 title "155Gd and 161Dy Mössbauer study of R1+εFe4B4 alloys (R = Gd, Dy)" @default.
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• W1990487434 doi "https://doi.org/10.1016/0038-1098(87)90964-1" @default.
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