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- W1990488603 abstract "The energy of combustion in fluorine of crystalline boric oxide was measured in a bomb calorimeter and found to be −(239.12±0.39) kcal mol−1. The enthalpies of solution in water of B2O3(c) and B2O3(amorph) to form H3BO3·341H2O(l) were found to be −(3.54±0.05) and −(7.98±0.04) kcal mol−1, respectively. These results were used to calculate the standard enthalpies of formation of crystalline and amorphous boric oxide, namely, ΔHfo(B2O3, c, 298.15 K) = −(304.48±0.59) kcal mol−1 and ΔHfo(B2O3, amorph, 298.15 K) = −(300.04±0.59) kcal mol−1. The values were further combined with values reported in the literature to derive ΔHfo(H3BO3, c) = −(261.71±0.31) kcal mol−1 and ΔHf(HF·3H2O, l) = −(76.71±0.08) kcal mol−1." @default.
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- W1990488603 date "1969-09-01" @default.
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- W1990488603 title "The enthalpies of formation of crystalline and amorphous boric oxide and orthoboric acid" @default.
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- W1990488603 doi "https://doi.org/10.1016/0021-9614(69)90004-4" @default.
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