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- W1990499557 abstract "The hydrogenation of (E)-2-(trifluoromethyl)alk-2-en-1-ols catalyzed by Ru-2, 2'-bis(diphynylphosphino)-1, 1'-binaphthyl (Ru-BINAP) and Rh-BINAP was carried out with good enantiomeric excess (71-83% ee). Ru-BINAP-catalyzed hydrogenation converted 2-(trifluoromethyl)acrylic acid to the corresponding saturated acid whose esterification and reduction provided optically active 2-(trifluoromethyl)propan-1-ol in 80% ee." @default.
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- W1990499557 date "2010-08-05" @default.
- W1990499557 modified "2023-09-25" @default.
- W1990499557 title "ChemInform Abstract: Preparation of Optically Active 2-(Trifluoromethyl)alkan-1-ols by Catalytic Asymmetric Hydrogenation." @default.
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- W1990499557 doi "https://doi.org/10.1002/chin.199634023" @default.
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