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- W1990507939 abstract "The solvus data for V-H and V-D exhibit an extended region of linearity when plotted as ln Z /sub a/ against T/sup -1/ where Z /sub a/ =(..cap alpha../..beta.. - ..cap alpha..)) where ..cap alpha.. is the H(D)-to-V, atom ratio, at the solvus composition and ..beta.. is the number of available interstices per metal atom. This behavior constrasts with the Ta-H system which exhibits considerable curvature in the solvus plot over the same temperature range. It is shown that the linearity results from the opposing influence of nonideality and the variation of the solvus enthalpy and entropy with temperature; the latter is due to the occupation of octahedral and tetrahedral interstices in the hydride and dilute phases, respectively. In contrast to the Ta-H(D) system, there is a solvus isotope effect in the V-H and V-D systems and this is explained in terms of the occupation of different interstices in the two coexisting phases." @default.
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- W1990507939 date "1985-04-01" @default.
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- W1990507939 title "Solvus behavior of the vanadium-hydrogen and deuterium systems" @default.
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- W1990507939 doi "https://doi.org/10.1016/0001-6160(85)90032-x" @default.
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