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- W1990531968 abstract "Abstract The magnetically ordered states in the oxygen-deficient YBa 2 (Cu 1- x Fe x ) 3 O y system (0.01≤ x ≤0.30) have been studied by Mossbauer spectroscopy. Magnetic ordering of Fe atoms is found at Cu(1) sites as well as at Cu(2) sites. At small iron concentrations x ≤0.05 the Cu(1) and Cu(2) sublattices are not coupled magnetically and two magnetic phase transitions are observed: the low-temperature transition for the Cu(1) sublattice at T m1 ≈20 K and the high-temperature transition for the Cu(2) sublattice at T m2 ≈400 K. With increasing iron concentration at x ≥0.10 a strong coupling between the Cu(1) and Cu(2) sublattices appears and the whole matrix is ordered antiferromagnetically with a single magnetic ordering point T m2 ≈460 K. The phase diagrams showing the regions of existence of different magnetic phases versus iron concentration are plotted for the oxygen-saturated and oxygen-reduced YBa 2 (Cu 1- x Fe x ) 3 O y systems." @default.
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- W1990531968 date "1992-09-01" @default.
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- W1990531968 title "Magnetic ordered states in the oxygen-deficient YBa2(Cu1-xFex)3Oy<6.5 system" @default.
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- W1990531968 doi "https://doi.org/10.1016/0921-4534(92)90414-8" @default.
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