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- W1990532010 endingPage "12734" @default.
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- W1990532010 abstract "Controlling chemical reactions with light rests on the idea of exciting a vibration that becomes the reaction coordinate in subsequent chemistry. Vibrational excitation techniques such as infrared or stimulated Raman excitation of fundamental vibrations or vibrational overtone excitation of higher levels permit the preferential cleavage of a bond in a photodissociation or bimolecular reaction. The key to bond-selected chemistry is the initial preparation of a suitable vibrational state followed, in the case of bond-selected photodissociation, by electronic excitation or, in the case of bond-selected bimolecular reaction, by collision with a reactive atom. Such experiments demonstrate bond-selected chemistry, permit detailed comparison to theory, and reveal general principles of vibrational state control of chemical reactions." @default.
- W1990532010 created "2016-06-24" @default.
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- W1990532010 date "1996-01-01" @default.
- W1990532010 modified "2023-10-03" @default.
- W1990532010 title "Bond-Selected Chemistry: Vibrational State Control of Photodissociation and Bimolecular Reaction" @default.
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- W1990532010 doi "https://doi.org/10.1021/jp9604812" @default.
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